safety data sheet - Fisher Scientific

SAFETY DATA SHEET
Creation Date 12-Feb-2015
Revision Date 04-Oct-2016
Revision Number 2
1. Identification
Product Name
1,4-Diazabicyclo[2.2.2]octane
Cat No. :
AC112470000; AC112470025; AC112470250; AC112471000;
AC112475000
Synonyms
Triethylenediamine; TED; BACO; Dabcoº4
Recommended Use
Laboratory chemicals.
No Information available
Uses advised against
Details of the supplier of the safety data sheet
Company
Fisher Scientific
One Reagent Lane
Fair Lawn, NJ 07410
Tel: (201) 796-7100
Entity / Business Name
Acros Organics
One Reagent Lane
Fair Lawn, NJ 07410
Emergency Telephone Number
For information US call: 001-800-ACROS-01
/ Europe call: +32 14 57 52 11
Emergency Number US:001-201-796-7100 /
Europe: +32 14 57 52 99
CHEMTREC Tel. No.US:001-800-424-9300 /
Europe:001-703-527-3887
2. Hazard(s) identification
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Flammable solids
Acute oral toxicity
Skin Corrosion/irritation
Serious Eye Damage/Eye Irritation
Category 2
Category 4
Category 2
Category 1
Label Elements
Signal Word
Danger
Hazard Statements
Flammable solid
Harmful if swallowed
Causes skin irritation
Causes serious eye damage
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Revision Date
1,4-Diazabicyclo[2.2.2]octane
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Precautionary Statements
Prevention
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Wear protective gloves/protective clothing/eye protection/face protection
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Ground/bond container and receiving equipment
Use explosion-proof electrical/ventilating/lighting/equipment
Skin
IF ON SKIN: Wash with plenty of soap and water
If skin irritation occurs: Get medical advice/attention
Take off contaminated clothing and wash before reuse
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Immediately call a POISON CENTER or doctor/physician
Ingestion
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
Rinse mouth
Fire
In case of fire: Use CO2, dry chemical, or foam for extinction
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
May form combustible dust concentrations in air
3. Composition / information on ingredients
Component
1,4-Diazabicyclo[2.2.2]octane
CAS-No
280-57-9
Weight %
>95
4. First-aid measures
Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Immediate medical attention is required.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes. Obtain medical attention.
Inhalation
Move to fresh air. Do not use mouth-to-mouth method if victim ingested or inhaled the
substance; give artificial respiration with the aid of a pocket mask equipped with a one-way
valve or other proper respiratory medical device. Obtain medical attention. If not breathing,
give artificial respiration.
Ingestion
Do not induce vomiting. Call a physician or Poison Control Center immediately.
Most important symptoms/effects
Breathing difficulties. Causes eye burns. Causes severe eye damage. Inhalation of high
vapor concentrations may cause symptoms like headache, dizziness, tiredness, nausea
and vomiting
Treat symptomatically
Notes to Physician
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Revision Date 04-Oct-2016
1,4-Diazabicyclo[2.2.2]octane
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5. Fire-fighting measures
Suitable Extinguishing Media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Cool closed
containers exposed to fire with water spray.
Unsuitable Extinguishing Media
No information available
Flash Point
Method -
62 °C / 143.6 °F
No information available
350 °C / 662 °F
Autoignition Temperature
Explosion Limits
No data available
Upper
No data available
Lower
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available
Specific Hazards Arising from the Chemical
Flammable. Risk of ignition. Dust can form an explosive mixture in air. Containers may explode when heated. Thermal
decomposition can lead to release of irritating gases and vapors. Keep product and empty container away from heat and sources
of ignition. Combustible material.
Hazardous Combustion Products
Nitrogen oxides (NOx) Carbon monoxide (CO) Carbon dioxide (CO2) Ammonia nitric acid
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
NFPA
Health
2
Flammability
3
Instability
1
Physical hazards
N/A
6. Accidental release measures
Personal Precautions
Environmental Precautions
Use personal protective equipment. Remove all sources of ignition. Avoid dust formation.
Take precautionary measures against static discharges. Ensure adequate ventilation. Avoid
contact with skin, eyes and clothing.
Avoid release to the environment. See Section 12 for additional ecological information.
Methods for Containment and Clean Remove all sources of ignition. Sweep up or vacuum up spillage and collect in suitable
container for disposal. Avoid dust formation. Use spark-proof tools and explosion-proof
Up
equipment.
7. Handling and storage
Handling
Use only under a chemical fume hood. Wear personal protective equipment. Use
spark-proof tools and explosion-proof equipment. Keep away from open flames, hot
surfaces and sources of ignition. Take precautionary measures against static discharges.
Do not get in eyes, on skin, or on clothing. Do not breathe vapors/dust. Do not ingest.
Storage
Keep away from heat and sources of ignition. Keep containers tightly closed in a dry, cool
and well-ventilated place. Flammables area.
8. Exposure controls / personal protection
Exposure Guidelines
Component
1,4-Diazabicyclo[2.2.2]octane
Mexico OEL (TWA)
Quebec
Ontario TWAEV
TWA: 1 ppm
TWA: 4.6 mg/m3
Skin
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Revision Date 04-Oct-2016
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Ensure adequate ventilation, especially in confined areas. Use explosion-proof
electrical/ventilating/lighting/equipment. Ensure that eyewash stations and safety showers
are close to the workstation location.
Engineering Measures
Personal Protective Equipment
Eye/face Protection
Wear appropriate protective eyeglasses or chemical safety goggles as described by
Skin and body protection
Wear appropriate protective gloves and clothing to prevent skin exposure.
Respiratory Protection
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice.
9. Physical and chemical properties
Solid
White
Ammonia-like
No information available
10.8 10g/l aq.sol
155 - 160 °C / 311 - 320 °F
174 °C / 345.2 °F @ 760 mmHg
62 °C / 143.6 °F
Not applicable
No information available
Physical State
Appearance
Odor
Odor Threshold
pH
Melting Point/Range
Boiling Point/Range
Flash Point
Evaporation Rate
Flammability (solid,gas)
Flammability or explosive limits
Upper
Lower
Vapor Pressure
Vapor Density
Specific Gravity
Solubility
Partition coefficient; n-octanol/water
Autoignition Temperature
Decomposition Temperature
Viscosity
Molecular Formula
Molecular Weight
No data available
No data available
2.9 mmHg @ 50 °C
Not applicable
1.140
No information available
No data available
350 °C / 662 °F
No information available
Not applicable
C6 H12 N2
112.17
10. Stability and reactivity
Reactive Hazard
None known, based on information available
Stability
Hygroscopic.
Conditions to Avoid
Keep away from open flames, hot surfaces and sources of ignition. Avoid dust formation.
Incompatible products. Exposure to moist air or water.
Incompatible Materials
Strong oxidizing agents, Peroxides, Acids, sodium hypochlorite, copper, Aldehydes
Hazardous Decomposition Products Nitrogen oxides (NOx), Carbon monoxide (CO), Carbon dioxide (CO2), Ammonia, nitric acid
Hazardous Polymerization
Hazardous polymerization does not occur.
Hazardous Reactions
None under normal processing.
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Revision Date 04-Oct-2016
1,4-Diazabicyclo[2.2.2]octane
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11. Toxicological information
Acute Toxicity
Product Information
Component Information
Component
1,4-Diazabicyclo[2.2.2]octane
LD50 Oral
700 mg/kg ( Rat )
LD50 Dermal
>2000 mg/kg (Rabbit)
LC50 Inhalation
>20 mg/L/1h (Rat)
No information available
Toxicologically Synergistic
Products
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation
Severe eye irritant; Irritating to skin
Sensitization
No information available
Carcinogenicity
The table below indicates whether each agency has listed any ingredient as a carcinogen.
Component
1,4-Diazabicyclo[2.2.2]
octane
CAS-No
280-57-9
IARC
Not listed
NTP
Not listed
Mutagenic Effects
Not mutagenic in AMES Test
Reproductive Effects
No information available.
Developmental Effects
No information available.
Teratogenicity
No information available.
STOT - single exposure
STOT - repeated exposure
None known
None known
Aspiration hazard
No information available
ACGIH
Not listed
OSHA
Not listed
Mexico
Not listed
Symptoms / effects,both acute and Inhalation of high vapor concentrations may cause symptoms like headache, dizziness,
tiredness, nausea and vomiting
delayed
No information available
Endocrine Disruptor Information
The toxicological properties have not been fully investigated.
Other Adverse Effects
12. Ecological information
Ecotoxicity
This product contains the following substance(s) which are hazardous for the environment. .
Component
1,4-Diazabicyclo[2.2.2]octan
e
Freshwater Algae
Not listed
Freshwater Fish
LC50: 1510 - 1980 mg/L,
96h flow-through
(Pimephales promelas)
Microtox
Not listed
Persistence and Degradability
Bioaccumulation/ Accumulation
Soluble in water Persistence is unlikely based on information available.
No information available.
Mobility
Will likely be mobile in the environment due to its water solubility.
Water Flea
Not listed
13. Disposal considerations
Waste Disposal Methods
Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, and
national hazardous waste regulations to ensure complete and accurate classification.
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1,4-Diazabicyclo[2.2.2]octane
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14. Transport information
DOT
UN-No
Proper Shipping Name
Proper technical name
Hazard Class
Packing Group
TDG
UN-No
Proper Shipping Name
Hazard Class
Packing Group
IATA
UN-No
Proper Shipping Name
Hazard Class
Packing Group
IMDG/IMO
UN-No
Proper Shipping Name
Hazard Class
Packing Group
UN1325
Flammable solid, organic, n.o.s.
1,4-Diazabicyclo[2.2.2]octane
4.1
II
UN1325
Flammable solid, organic, n.o.s.
4.1
II
UN1325
Flammable solid, organic, n.o.s
4.1
II
UN1325
Flammable solid, organic, n.o.s
4.1
II
15. Regulatory information
All of the components in the product are on the following Inventory lists: X = listed
International Inventories
Component
TSCA
1,4-Diazabicyclo[2.2.2]octane
X
DSL
X
NDSL EINECS ELINCS
205-999-9
-
NLP
PICCS
X
ENCS
X
AICS
X
IECSC
X
KECL
X
Legend:
X - Listed
E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA.
F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA.
N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated
polymer made with any free-radical initiator regardless of the amount used.
P - Indicates a commenced PMN substance
R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA.
S - Indicates a substance that is identified in a proposed or final Significant New Use Rule
T - Indicates a substance that is the subject of a Section 4 test rule under TSCA.
XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base
Production and Site Reports (40 CFR 710(B).
Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater.
Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants
that comprises one of the eligibility criteria for the exemption rule.
U.S. Federal Regulations
TSCA 12(b)
Not applicable
SARA 313
Not applicable
SARA 311/312 Hazard Categories
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
Sudden Release of Pressure Hazard
Reactive Hazard
CWA (Clean Water Act)
Yes
No
Yes
No
No
Not applicable
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1,4-Diazabicyclo[2.2.2]octane
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Clean Air Act
Not applicable
OSHA Occupational Safety and Health Administration
Not applicable
CERCLA
Not applicable
California Proposition 65
This product does not contain any Proposition 65 chemicals
U.S. State Right-to-Know
Regulations
Not applicable
U.S. Department of Transportation
Reportable Quantity (RQ):
DOT Marine Pollutant
DOT Severe Marine Pollutant
N
N
N
U.S. Department of Homeland Security
This product does not contain any DHS chemicals.
Other International Regulations
Mexico - Grade
No information available
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and
the MSDS contains all the information required by the CPR
WHMIS Hazard Class
B3 Combustible liquid
D2B Toxic materials
E Corrosive material
Prepared By
Regulatory Affairs
Thermo Fisher Scientific
Email: [email protected]
Creation Date
Revision Date
Print Date
Revision Summary
12-Feb-2015
04-Oct-2016
04-Oct-2016
This document has been updated to comply with the US OSHA HazCom 2012 Standard
replacing the current legislation under 29 CFR 1910.1200 to align with the Globally
Harmonized System of Classification and Labeling of Chemicals (GHS)
16. Other information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text
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