HOJA DE SEGURIDAD DEL PRODUCTO UAN

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ADMINISTRACIÓN: AV. PIO X 99
PLANTA INDUSTRIAL: COMPLEJO F.M.R.T. DIVISIÓN QUIMICA
(5850) RIO TERCERO - PCIA. DE CORDOBA – TEL.: 03571-423532 Y ROT.
e-mail: [email protected]
SAFETY DATA SHEET FOR APORTE HEXA-K
NFPA Classification
Transport of dangerous
materials – Agreement
MERCOSUR
Elements of Personal Protection
Ref. UN 2506 control form N° 80
Eye protection: safety glasses.
0
1
Respiratory
0
protection:
semi-mask
with filter for ammonia (if entering in a
tank)
Hand protection: PVC gloves
SECTION I - CHEMICAL PRODUCT – IDENTIFICATION OF THE
COMPANY
Name of the Product: AQUOEUS SOLUTION OF INORGANIC SALTS
Comercial name: APORTE HEXA K
SYNOMYM: aqueous solution of inorganic salts
Chemical formula:
Chemical Name:
Chemical Family:
Aqueous solution of inorganic Aqueous
solution
salts
inorganic salts
of Ammonium sulfate: (NH4)2SO4
Monoammonium phosphate
(NH4)H2PO4
Potassium sulfate: K2SO4
Zinc sulfate: ZnSO4
Ammonium borate: (NH4)2B4O7
Manufacturer: BUFFON S.A.
Distributor:
Emergency Telephone: 54-3571-432100
Cel: 54-3571-15575107
Uses: Fertilizer
Transport: DANGEROUS MATERIALS
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Medical Attention:
*FEDERAL CAPITAL
TOXICOLOGICAL CENTERS
*CORDOBA
*CATAMARCA
Hospital Pedro de Elizalde
Montes de Oca 40 cap. Fed.
Tel.011-4321-2115 Toxicología
Tel.011-4321-2115 Toxicología
Hospital de Niños
Gallo 1130 Cap. Fed.
Tel. 011-4962-6666/2247
Toxicología
Hospital de Niños
Corrientes 643 cba
Tel.0351-423-3303 guardia
0351-4229961 conmutador
Hospital de Urgencias
Catamarca 411 Córdoba
Tel. 0351-422-2039/21/0243
*BUENOS AIRES
Hospital Municipal Infantil
Lavalleja 3000 – Córdoba
Tel. 0351-471-8785/8852/6492
Toxicología
*LA RIOJA
*SALTA
*MENDOZA
Hospital San Bernardo
Tobías 69 – Salta
Tel. 0387-422-4254/22 - 4316
Hospital Central
Alem y Salta - Mendoza
Hospital de Niños
Sarmiento 629 – Salta
Tel. 0387- 3954
Hospital Emilio Civil
Parque Gral. San Martín –
Mendoza
Tel. 0361-4252476/4250476
Policlínico Posadas
Pte. Arturo M.Illia y
MARCONI
Haedo Bs.As.
Tel. 011-4658-7777 y 4654-6648
Toxicología
011-4658-3001 al 06
conmutador
Hospital de Niños de La Plata
Calle 14 entre 65 y 66 - La
Plata
Buenos. Aires.
Tel.221-451-5555
*SANTA FE
Centro de Toxicología
Tucumán 1544 – Rosario
Tel. 0341- 4242727
Conmutador
Hospital de niños
Av. Urquiza 1050 Cat.
Tel.03833-425118
*JUJUY
Centro de Toxicología
San Martín y Alberdi
San Salvador de Jujuy
Tel. 03822-428310
Hospital Pte. La Plaza
Av. San Nicolás de Bari 97
La Rioja
Tel.03822-427814
SECTION II - TOXICOLOGOCAL COMPONENTS
Toxicological Information on the components: its components are non-toxic. They are
not edible products.
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SECTION III - IDENTIFICATIÓN OF DANGERS
Acute health effects
None known
Chronic effect potential
None known
SECTION IV - FIRST AID MEASURES
Contact with the Light irrigation; wash with copious amounts of water for 15
eyes
minutes.
Minor skin contact
Light irrigation; wash with copious amounts of water, remove
clothing wet by the product.
Prolonged
skin Irrigation of persons affected; wash with copious amounts of
contact
water and seek medical attention.
Minor inhalation
Slight irritation; remove to welle ventilated area.
Severe inhalation
Irritation & inflamation of upper respiratory tract. Remove to
well ventilated area and seek medical attention.
Light ingestion
Low toxicity. May cause nausea or diarreah by irritation. If the
victim if conscience, drink copious amounts of water.
Severe ingestion
If the victim is conscience, drink copious amounts of water, but
do not induce vomiting, sep medical help. Never administer
liquids to unconscience victims, semi-conscience or fainting.
SECCIÓN V - INFORMACIÓN SOBRE FUEGO Y EXPLOSIÓN
Not applicable
Flamability
Auto-ignition temperature Not applicable
Not applicable
Flash point
Not applicable
Flamability limits
Non-flamable, but decomposes into toxic and/or
Combustión products
inflamable gases (ammonia & nitrogen oxides) near high
temperature sources. The solid residue after evaporation
of water contains ammonium nitrate, an explosive
propellant at high temperatures or in the presence of
strong oxidizers.
Not applicable
Danger of fire in the
presence of different
substances
Danger of explosion in the Not explosive
presence of different
sustances
Not applicable
Fire control
Special observations in the Not applicable
case of FIRE danger
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Special observations in Not applicable
case of danger of explsion
SECTIÓN VI - MEASURES IN CASE OF ACCIDENTAL SPILLS
Wash into sewers with excess water or deposit in compost
Small spills
piles.
Collect contaminated soil and remove to authorized
Large spills
deposits, especially land fills or deposits where mateerials
are recovered for use as plant nurients. Control water
tables and surface water to to insure against
contamination.
SECTION VII - HANDLING AND STORAGE
Use eye protection, impermeable gloves and proper
Handling
clothing to minimize coantact with the skin.
The product is corrsive to yellow metals, bronz, copper
Storage
and tin. Do not use tools, valves or conduits made of tose
materials. Proper materials include stainless steel,
common iron and steel, plastics and porcelan. Caution:
Do not weld tanks that have contained UAN without
previously washing them out with large amounts of water.
Do not allow tanks temperatures to exceed 100° C. Sep
tanks isolated from imcompatible materials.
SECTIÓN VIII – WORK CONDITIONS AND ELEMENTS OF PERSONAL
PROTECTION
Work in web ventilated areas.
Work conditions
Eye protection: safety glasses, PVC gloves, long sleeved
Personal protection
shirt, impermeable arpón or impermeable clothes when
operating vlaves, and, where necessary, portable
respirators with ammonia filtres when entering empty
tanks.
Impermeable
boots and clothing, safety glasses,
Personal protection in
respiratory protection.
emergencies
Not applicable
Exposure limits
SECTIÓN IX - PHYSICAL STATE - ASPECT
3.8
pH
Vapor pressure
100° C
Boiling point
Color
S/D
Colorless
5
-5° C
Melting point
Odor
S/D
Critical
Water solubility
Temperature
Density 0° C, 1 atm 1.24 g/ ml
Odorless
Soluble in all proportions
SECTIÓN X – INFORMATION ON STABILITY AND REACTIVITY
Stable
Stability
Decomposes above 100° C, avoid over
Stability at elevated temperatures
heating.
Chlorine, hypochlorite, metallic powders
Incompatibilty with other substances
containing Cd, Cu, Pb, Ni, Co, Bi, Cr, Mg,
Zn, Al.
Corrodes bronze, copper, tin and similar
Corrosivity
materials.
SECTIÓN XI – TOXICOLOGICAL INFORMATION
Ingestion, continuous skin contact,
Significant routes of exposure
splatters in the eyes, inhalation in closed
environments and confined spaces.
Does not exhibit toxcity in normal use
Toxicity in animals
None identified
Other effects in humans
Special observations on other chronic Not applicable
effects in humans
Special observations on other effects in None identified
humans
SECTIÓN XII – ECOLOGICAL INFORMATION
No accumulative effect in normal use in agriculture.
Ecotoxicity
Aquatic toxicity: disperses and dissolves easily. In
high concentrations promotes excessive algal growth
and eutrophication. Degradation products may be
toxic to fish, so its discharge in surface water should
be avoided. Is not a marine contaminant.
Nitrogen oxides, ammonia.
Decomposition products
Toxicity of decomsposition The product and its decomposition products are not in
themselves dangerous under normal use conditions.
products
Spills into surface water should be avoided.
Special
observations
on Algal growth may worsen water quality in terms of
turbidity and flavor.
decomposition products
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SECTIÓN XIII - RESIDUES
Residues in water and recylcling
SECTIÓN XIV - TRANSPORT
National Transport law 24.449
Special provisions for transport
Recycle all residues possible to the farm
soil. Comply with all national, provential
and municipal ordanances with respect to
effulients.
General cargos
Not applicable
SECTIÓN XV – REGULATIONS AND SIGNS
Not applicable
NFPA
Not applicable
TDG Signs MERCOSUR
References
MERCOSUR Agrement on the Transport of Dangerous Materials
National Transportation Law 24.449
Technical Resolution 195/97 Technical regulations
Law 19.587/72 Security and Higeine In the Workplace
Decree 351/79 Reglamentation of Law 19.587/72
NOTE TO READERS
The purchaser assumes all risk related to the use of this material. The purchaser is
responsible for the safe use of the product, adherence to applicable legislation with
regard to the environment and safety and security in the work place.
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GUIDE TOXIC AND CORROSIVE SUBSTANCES (NON-FLAMABLE)
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POTENTIAL DANGERS
TO HEALTH
· Toxic; the inhalation, ingestión or contact of the material with the skin may cause severe lessions or
death.
· Contact with the meted material may cause severe burns to the skin and eyes.
· Avoid all contact with the skin.
· The effects of contact or inhalation may appear some time after contact.
· Fire may produce irritating, corrosive and/or toxic gases.
· Escapes resulting from the control of fires o dilution with water may be corrosive and/or toxic and cause
contamination.
_____________________________________________________________________________________
FIRE OR EXPLOSION
· The non-combustible substances will not ignite alone. But may decompose when heated and produce
corrosive and/or toxic gases.
·Some components are oxidizers and may ignite other combustible materials (wood, oils, clothing, etc.)
· Contact with metals may give Of. Inflamable hydrogen gas.
· Containers may explode when heated.
PUBLIC SAFETY
· First call the emergency response telephone number in the shipping documents. If the shipping
document is not available or there is no answer, call the numbers naoted on the back of the
container or technical literature.
· Isolate the spill or escape area immediately for a radial distance of at least 25-30 meters (80-160feet).
· Sep all unauthorized persons Hawai from the area.
· Remain up wind of the spill.
· Stay Hawai from low lying areas.
· Ventilate enclosed areas.
_____________________________________________________________________________________
PROTECTIVE CLOTHING
· Use autonomous, ppositive pressure respiratory equipment ( SCBA).
· Use protective clothing suitable for chemical products as recommended by the manufacturer. This may
provide little or no termal protection.
· The strandard fire fighter’s clothing provides limited protection ONLY in fire situations and is not
effects in the case of spills.
_____________________________________________________________________________________
EVACUATION
Spills:
· See initial isolation and protective action distance tables for the substances released.
For other substances, increase the isolation distance given in “PUBLIC SAFETY” as necessary in the
prevailing wind direction.
Fire
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· If a tank, railcar or car tank is involved in the FIRE, isolate the area to a radius of 800 meters (1/2 mile)
as well, consider the initial evacuation radius to be 800 meters (1/2 mile) as well.
GUIDE
154
TOXIC AND/OR CORROSIVE SUBSTANCES (NON-COMBUSTABLE)
EMERGENCY RESPONSE
FIRE
Small fires
· dry chemical, CO2 or spray with water.
Large fires
· Use dry chemical, CO2, water spray or alcohol resistant foam.
·Remove non-involved containers from the area of the FIRE if posible without risk.
· Make a retention dam for the FIRE control water for later waste control; do not scatter the material.
FIRE involving tanks railcars or trailers and their cargos
Combate the FIRE from the maximum distance o utilize fixed supports to maintain the hoses and regulating
valves (chiflones??).
· Do not introduce water incide the containers.
· Cool the contaiiners with streams of water until web after the FIRE has been extinguished.
· Evacuate the area immediately if there is a growing sound coming from the security mechanism of the
ventílelas (¿?) or if the tank beginf to discolor.
· AÑWAYS remain well away from tanks involved in fire.
____________________________________________________________________________________________________________
SPILL OR LEAK
· Eleminate all posible sources of ignition (do not smoke, use flares,spaks or flames in the area of the
danger.
· Do not touch the damaged containers or spilled materials unless using adequate protective clothing.
· Stop the leak, if it can be done without risk.
· Prevent entry of the leaked or spilled materials into navegable waterways, drainage ditches, basements or
other confined areas.
· Absorb the spilled materials with dry dirt, sand or other non-flamable absorbent materials and transfer to
suitable containers.
· DO NOT INTRODUCE WATER INTO THE LEAKING CONTAINERS.
____________________________________________________________________________________________________________
FIRST AID
· Remove the victim to an open area where they can breath fresh air.
· Call emergency medicalservices.
· Apply artificial respiration if the victim is not breathing.
· Do not use mouth-to-mputh respiration if the victim has ingested or inhaled the material; apply respiration
with the help of a one way valve or other artificial apparatus for tmedical respiration.
· Supply oxygen if respiration is difficult.
· Remove and isolate contaminated clothing and shoes.
· In case of contact with the substance, rinse the skin or eyes with a stream of water for 20 minutes.
· For minor skin contact, avoid spreading the material on unaffected skin areas.
· Maintain the victim lying down and at normal temperature.
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· The effects of exposure to the substance (inhalation, ingestión or contact with the skin) may produce
delayed symptoms.
· Insure that medical personnel are aware of the nature of the materials involved and take precautions to
protect them.

HOJA DE SEGURIDAD DEL PRODUCTO UAN

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